692786

(S,S)-DACH-naphthyl Trost Ligand

95%

• Synonym(s): (1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphino-1-naphthoyl)
• Empirical Formula (Hill Notation): C₅₂H₄₄N₂O₂P₂
• CAS Number: 205495-66-5
• Molecular Weight: 790.87
• MDL number: MFCD02684552
• UNSPSC Code: 12352005
• PubChem Substance ID: 329761527
• NACRES: NA.22

Properties

• assay: 95%
• form: solid
• optical activity: [α]20/D -66.0°, c = 1 in methanol
• mp: 232-237 °C
• functional group: amide; phosphine
• SMILES string: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
• InChI: 1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1
• InChI key: VXFKMKXTPXVEMU-ZYBCLOSLSA-N

Description

Application

Trost Ligands for Asymmetric Allylic Alkylation

Asymmetric allylic alkylation ligand.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable