692808

(R,R)-DACH-phenyl Trost ligand

95%

• Synonym(s): (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)
• Empirical Formula (Hill Notation): C₄₄H₄₀N₂O₂P₂
• CAS Number: 138517-61-0
• Molecular Weight: 690.75
• MDL number: MFCD01631273
• UNSPSC Code: 12352002
• PubChem Substance ID: 329761529
• NACRES: NA.22

Properties

• assay: 95%
• form: solid
• optical activity: [α]20/D +131°, c = 1 in methanol
• mp: 136-142 °C
• functional group: amide; phosphine
• SMILES string: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
• InChI key: AXMSEDAJMGFTLR-XRSDMRJBSA-N

Description

Application

Trost Ligands for Asymmetric Allylic Alkylation

Asymmetirc allylic alkylation ligand.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable