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Sigma-Aldrich

Naphthenic acid

technical

Synonym(s):

Acidol (petroleum by-product), Sunaptic B

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About This Item

CAS Number:
EC Number:
MDL number:
UNSPSC Code:
12352100
NACRES:
NA.22

grade

technical

form

liquid

acid value

~215

density

0.92 g/mL at 20 °C (lit.)

InChI

1S/C10H18O2/c1-2-8-3-4-9(7-8)5-6-10(11)12/h8-9H,2-7H2,1H3,(H,11,12)

InChI key

WVRFSLWCFASCIS-UHFFFAOYSA-N

Application

Naphthenic acid is commonly used in the synthesis of useful metal naphthenates such as copper naphthenate, a wood preservative; titanium naphthenate, a precursor for the preparation of titanium oxide thin films and a rare earth naphthenate, a lubricant oil additive. It can also be in the synthesis of biodegradable naphthenic acid ionic liquids.

Analysis Note

petroleum product, techn. mixture of alkylated cyclopentane carboxic acids

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

213.8 °F - closed cup

flash_point_c

101 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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Steven D Melvin et al.
Environmental pollution (Barking, Essex : 1987), 177, 22-27 (2013-03-08)
Naphthenic acids (NA) are used in a variety of commercial and industrial applications, and are primary toxic components of oil sands wastewater. We investigated developmental and metabolic responses of tadpoles exposed to sub-lethal concentrations of a commercial NA blend throughout
Navdeep S Toor et al.
Environmental toxicology and chemistry, 32(10), 2207-2216 (2013-06-05)
The toxicity of oil sands process-affected waters (OSPW) from the Athabasca Oil Sands (AOS) in northern Alberta, Canada, is related to a relatively persistent group of dissolved organic acids known as naphthenic acids (NAs). Naphthenic acids are a complex mixture
Hideo Kawaguchi et al.
Water research, 46(17), 5566-5574 (2012-08-21)
The in situ oil sands production method called steam-assisted gravity drainage (SAGD) reuses process wastewater following treatment. However, the treatment and reuse processes concentrate contaminants in the process water. To determine the concentration and dynamics of inorganic and organic contaminants
Teresa Misiti et al.
Water research, 47(1), 406-418 (2012-11-09)
Naphthenic acids (NAs) are a complex group of alkyl-substituted acyclic, monocyclic and polycyclic carboxylic acids present in crude oil, oil sands process water and tailings ponds, as well as in refinery wastewater. Bioassays were performed to investigate the biotransformation potential
Preparation of titanium oxide layer on silica glass substrate with titanium naphthenate precursor.
Hwang K S, et al.
Journal of Sol-Gel Science and Technology, 35(3), 237-243 (2005)

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