753343

[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)

95%

• Synonym(s): [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), IPrAuNTf₂, [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold
• Empirical Formula (Hill Notation): C₂₉H₃₇AuF₆N₃O₄S₂
• CAS Number: 951776-24-2
• Molecular Weight: 866.71
• MDL number: MFCD22572651
• UNSPSC Code: 12161600
• PubChem Substance ID: 329766355
• NACRES: NA.22

Properties

• assay: 95%
• form: solid
• reaction suitability: core: gold; reagent type: catalyst
• mp: 202-287 °C (decomposition)
• SMILES string: CC(C)c1cccc(C(C)C)c1N2C=CN(C2=[Au]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)c3c(cccc3C(C)C)C(C)C
• InChI: 1S/C27H36N2.C2F6NO4S2.Au/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h9-16,18-21H,1-8H3;;/q;-1;+1
• InChI key: FLIVFZVCPOQPDV-UHFFFAOYSA-N

Description

Application

Selective Au(I) catalyst for hydroaminations.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable