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Sigma-Aldrich

Lithium phosphorus sulfur chloride (LPSCl) powder

battery grade

Synonym(s):

Argyrodite solid electrolyte

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About This Item

Empirical Formula (Hill Notation):
Li6PS5Cl
CAS Number:
1015037-41-8
Molecular Weight:
268.40
UNSPSC Code:
12352300
NACRES:
NA.23

grade

battery grade

Quality Level

100

assay

≥99.5%

form

powder

mol wt

Mw 268.40 g/mol

composition

Li6PS5Cl

conductivity

0.01-0.1  mS/cm (ionic conductivity, cold-pressed pellet at room temperature)

density

1.64 g/cm3 (lit.)

application(s)

battery manufacturing

General description

Lithium phosphorus sulfur chloride (LPSCl) is a light brown powder that features high ionic conductivity. LPSCl belongs to the Argyrodite-type crystal structure, which is a type of cubic close-packed structure, and facilitates fast lithium-ion diffusion. LPSCl has a molecular weight of 268.40 g/mol and a density of 1.64 g/cm3 (lit.). Importantly, LPSCl is compatible with lithium metal anodes.

Application

Lithium phosphorus sulfur chloride is primarily used as a solid-state electrolyte for lithium-ion batteries due to its high ionic conductivity, high thermal stability, wide electrochemical window, and compatibility with lithium metal anodes. With the growing demand for high-performance batteries for use in electric vehicles, portable electronics, and other applications, Li6PS5Cl is positioned to play a key role in the future of battery technology. Its ability to enable the use of lithium metal anodes and solid-state electrolytes makes it an essential material for the development of next-generation batteries that offer increased energy efficiency, longer lifetimes, and improved safety.

Features and Benefits

Our battery grade Li6PS5Cl can help accelerate your research on solid-state or hybrid batteries and achieve reproducible performance:
  • High Ionic Conductivity
  • Consistent Particle Size
  • Wide Electrochemical Window
  • Compatible with Lithium Metal Anodes

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Water-react 1

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6327
MKCV6310
MKCV0685
MKCT1621
MKCT9388

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Mechanosynthesis of Solid Electrolytes: Preparation, Characterization, and Li Ion Transport Properties of Garnet-Type Al-Doped Li7La3Zr2O12 Crystallizing with Cubic Symmetry.
Duvel A, et al.
The Journal of Physical Chemistry C, 116(29), 15192-15202 (2012)
Mechanosynthesis of Solid Electrolytes: Preparation, Characterization, and Li Ion Transport Properties of Garnet-Type Al-Doped Li7La3Zr2O12 Crystallizing with Cubic Symmetry
Duvel A, et al.
The Journal of Physical Chemistry C, 116(29), 15192-15202 (2012)
Lithium battery chemistries enabled by solid-state electrolytes
Manthiram A, et al.
Nature Reviews. Materials, 16103-16103 (2017)

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