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925497

Sigma-Aldrich

[Ir(dFOMeppy)2(dtbbpy)]PF6

≥95%

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About This Item

Empirical Formula (Hill Notation):
C42H40F10IrN4O2P
CAS Number:
1809326-18-8
Molecular Weight:
1045.97
UNSPSC Code:
12352101
NACRES:
NA.22

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

Application

[Ir(dFOMeppy)2(dtbbpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor

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Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

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Chi Chip Le et al.
Journal of the American Chemical Society, 137(37), 11938-11941 (2015-09-04)
In this study we demonstrate that molecular fragments, which can be readily coupled via a simple, in situ RO-C═OR bond-forming reaction, can subsequently undergo metal insertion-decarboxylation-recombination to generate Csp(2)-Csp(3) bonds when subjected to metallaphotoredox catalysis. In this embodiment the conversion

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