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Key Documents

C54007

Sigma-Aldrich

Chloromethyl methyl sulfide

95%

Synonym(s):

Chlorodimethyl sulfide

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About This Item

Linear Formula:
CH3SCH2Cl
CAS Number:
Molecular Weight:
96.58
Beilstein/REAXYS Number:
1730851
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

assay

95%

form

liquid

refractive index

n20/D 1.498 (lit.)

bp

105 °C (lit.)

density

1.153 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CSCCl

InChI

1S/C2H5ClS/c1-4-2-3/h2H2,1H3

InChI key

JWMLCCRPDOIBAV-UHFFFAOYSA-N

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Application

Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.

Caution

May darken in storage.

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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Synthesis, 276-276 (1994)
Organic Syntheses, 70, 177-177 (1992)
Manuel Algarra et al.
The journal of physical chemistry. A, 124(10), 1911-1921 (2020-02-14)
UV photodecomposition of azidomethyl methyl sulfide (AMMS) yields a transient S-methylthiaziridine which rapidly evolves to S-methyl-N-sulfenylmethanimine at 10 K. This species was detected by infrared matrix isolation spectroscopy. The mechanism of the photoreaction of AMMS has been investigated by a
Chemistry Letters (Jpn), 653-653 (1993)
[Mutagenic activity of chlorodimethylsulfide and some of its aniline derivatives].
M Vito et al.
Bollettino della Societa italiana di biologia sperimentale, 61(6), 917-923 (1985-06-30)

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