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M73206

Sigma-Aldrich

4-Methylpiperidine

96%

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Synonym(s):
γ-Pipecoline, 4-Pipecoline
Empirical Formula (Hill Notation):
C6H13N
CAS Number:
Molecular Weight:
99.17
Beilstein/REAXYS Number:
1083
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

124 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

SMILES string

CC1CCNCC1

InChI

1S/C6H13N/c1-6-2-4-7-5-3-6/h6-7H,2-5H2,1H3

InChI key

UZOFELREXGAFOI-UHFFFAOYSA-N

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1 of 4

This Item
131490A75684245739
vibrant-m

M73206

4-Methylpiperidine

vibrant-m

131490

4-Methylpyridine

vibrant-m

A75684

2-Amino-5-methylpyridine

vibrant-m

245739

4,4′-Dimethyl-2,2′-dipyridyl

assay

96%

assay

98%

assay

99%

assay

99%

form

liquid

form

liquid

form

crystals

form

solid

bp

124 °C (lit.)

bp

145 °C (lit.)

bp

227 °C (lit.)

bp

-

density

0.838 g/mL at 25 °C (lit.)

density

0.957 g/mL at 25 °C (lit.)

density

-

density

-

refractive index

n20/D 1.446 (lit.)

refractive index

n20/D 1.504 (lit.)

refractive index

-

refractive index

-

Application

4-Methylpiperidine can be used to synthesize the following bioactive compounds:
  • dimethyl bis(4-methylpiperidine-dithiocarbamato-S,S′)-tin(IV)
  • (E)-4-(4′-methylpiperidino-N-alkoxy) stilbenes
  • 4-methylpiperidinoalkylthio and 4-methylpiperidinoalkoxy derivatives of (E)-chalcone

It can also act as a deprotecting reagent for the removal of Fmoc group from amino acids during solid-phase peptide synthesis.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Preparation, Spectroscopy, Antimicrobial Assay, and X-Ray Structure of Dimethyl bis-(4-methylpiperidine dithiocarbamato-S, S)-tin (IV).
REHMAN Z, et al.
Turkish Journal of Chemistry, 31(4), 435-442 (2007)
Synthesis and antimicrobial activity of new (E)-4-[piperidino (4'-methylpiperidino-, morpholino-) N-alkoxy] stilbenes.
Wyrzykiewicz E, et al.
European Journal of Medicinal Chemistry, 41(4), 519-525 (2006)
Efficient synthesis of peptides with 4-methylpiperidine as Fmoc removal reagent by solid phase synthesis.
Galeano V, et al.
Journal of the Mexican Chemical Society, 58(4), 386-392 (2014)
Synthesis, physicochemical properties and antimicrobial evaluation of new (E)-chalcones.
Nowakowska Z, et al.
European Journal of Medicinal Chemistry, 43(4), 707-713 (2008)
Aline de Souza et al.
Drug delivery and translational research, 10(6), 1771-1787 (2020-08-26)
Peptide-mediated targeting to colorectal cancer can increase selectivity and specificity of this cancer diagnosis acting as biomarkers. The present work aimed to select peptides using the phage display technique and associate the peptides with polymeric nanospheres in order to evaluate

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