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8.22287

Sigma-Aldrich

Hydrogen peroxide 30%

(stabilized) for synthesis

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Synonym(s):
Hydrogen peroxide solution, Perhydrol
Empirical Formula (Hill Notation):
H2O2
CAS Number:
Molecular Weight:
34.01
Beilstein:
3587191
MDL number:

vapor pressure

18 hPa ( 20 °C)
23.3 mmHg ( 30 °C)

Quality Level

form

liquid

reaction suitability

reagent type: oxidant

pH

2-4 (20 °C in H2O)

bp

107 °C/1013 hPa

mp

-26 °C

density

1.11 g/cm3 at 20 °C

storage temp.

2-25°C

SMILES string

OO

InChI

1S/H2O2/c1-2/h1-2H

InChI key

MHAJPDPJQMAIIY-UHFFFAOYSA-N

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1 of 4

This Item
1.072101.93407HX0640
Hydrogen peroxide 30% (Perhydrol™) (stabilized for higher storage temp.) for analysis EMSURE ISO

Supelco

1.07210

Hydrogen peroxide 30%

Hydrogen peroxide EMPLURA®

Supelco

1.93407

Hydrogen peroxide

form

liquid

form

-

form

-

form

liquid

pH

2-4 (20 °C in H2O)

pH

≤3.5 (20 °C in H2O)

pH

-

pH

-

bp

107 °C/1013 hPa

bp

107 °C/1013 hPa

bp

-

bp

-

mp

-26 °C

mp

-25.7 °C

mp

-

mp

-

density

1.11 g/cm3 at 20 °C

density

1.11 g/cm3 at 20 °C

density

-

density

-

Application

Hydrogen peroxide 30% can be used as an oxidizing agent:
  • To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H2SO4.
  • For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.
  • For the epoxidation of terminal olefins using a mixture of Na2WO4 dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.
  • To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H2WO4 as a catalyst.
  • To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.

Analysis Note

Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Dam. 1

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

not combustible

Flash Point(C)

not combustible


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Customers Also Viewed

Slide 1 of 6

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Baeyer-Villiger-oxidation of cyclopentanone with aqueous hydrogen peroxide by acid heterogeneous catalysis
Fischer J and Holderich WF
Applied Catalysis A: General, 180(1-2), 435-443 (1999)
Handling hydrogen peroxide oxidations on a Large Scale: synthesis of 5-bromo-2-nitropyridine
Agosti A, et al.
Organic Process Research & Development, 21(3), 451-459 (2017)
Oxidation of sulfides to sulfoxides and sulfones with 30% hydrogen peroxide under organic solvent-and halogen-free conditions
Sato K, et al.
Tetrahedron, 57(13), 2469-2476 (2001)
A green method of adipic acid synthesis: organic solvent-and halide-free oxidation of cycloalkanones with 30% hydrogen peroxide
Usui Y and Sato K
Green Chemistry, 5(4), 373-375 (2003)
A Practical Method for Epoxidation of Terminal Olefins with 30 Hydrogen Peroxide under Halide-Free Conditions.
Kazuhiko Sato et al.
The Journal of organic chemistry, 61(23), 8310-8311 (1996-11-15)

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