Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

LX0350

Supelco

Lithium Hydroxide, Monohydrate

Meets ACS Specifications GR ACS

Synonym(s):

Lithium Hydroxide, Monohydrate, Lithium Hydroxide

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
HLiO · xH2O
CAS Number:
Molecular Weight:
23.95 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
EC Index Number:
215-183-4

Quality Level

assay

≥98.0%

form

crystals

impurities

≤0.01% Insoluble matter

color

white

pH

12 (50 °C, 50 g/L in H2O)

bp

924 °C/1013 hPa (decomposition)

mp

424 °C

solubility

124 g/L

anion traces

chloride (Cl-): ≤0.01%
lithium carbonate (Li2CO3): ≤2%
sulfate (SO42-): ≤0.05%

cation traces

Fe: ≤0.002%
heavy metals: ≤0.002%

shipped in

ambient

storage temp.

room temp

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

Application

Lithium Hydroxide, Monohydrate can be used as:
  • A catalyst to synthesize 3,4-disubstituted pyrrole derivatives by reacting with aromatic aldehydes and enolisable ketones via in situ formation of chalcones.
  • A precursor for the fabrication of lithium-ion battery cathode material.
  • A starting material to synthesize lithium cobalt oxide (LiCoO2, a positive electrode material) by hydrothermal reaction with cobalt (II) nitrate and hydrogen peroxide.

Analysis Note

Assay: 98.0% min
Chloride (Cl): 0.01% max
Color: White
Form: Crystals
Heavy Metals (by ICP-OES): 0.002% max
Insoluble matter: 0.01% max
Iron (Fe): 0.002% max
Lithium carbonate (Li2CO3): 2.0% max
Sulfate (SO4): 0.05% max

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Hydrothermal synthesis of LiCoO2 for lithium rechargeable batteries
Burukhin A, et al.
Solid State Ionics, 151(1-4) (2002)
Production of Battery Grade Lithium Hydroxide Monohydrate Using Barium Hydroxide Causticizing Agent
Liu H and Azimi G
Resources, Conservation and Recycling, 179 (2022)
Lithium hydroxide mediated synthesis of 3, 4-disubstituted pyrroles
Sharma R, et al.
Royal Society of Chemistry Advances, 3(34) (2013)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service