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13259

Supelco

Dimethyl carbonate

greener alternative

analytical standard

Synonym(s):

Carbonic acid dimethyl ester

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About This Item

Linear Formula:
(CH3O)2CO
CAS Number:
Molecular Weight:
90.08
Beilstein/REAXYS Number:
635821
EC Number:
MDL number:
UNSPSC Code:
77101502
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3.1 (vs air)

vapor pressure

18 mmHg ( 21.1 °C)

assay

≥99.0% (GC)

shelf life

limited shelf life, expiry date on the label

greener alternative product characteristics

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

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technique(s)

HPLC: suitable
gas chromatography (GC): suitable

impurities

≤0.02% water

refractive index

n20/D 1.368 (lit.)
n20/D 1.369

bp

90 °C (lit.)

mp

2-4 °C (lit.)

density

1.069 g/mL at 25 °C (lit.)

application(s)

environmental
pharmaceutical

format

neat

greener alternative category

SMILES string

O=C(OC)OC

InChI

1S/C3H6O3/c1-5-3(4)6-2/h1-2H3

InChI key

IEJIGPNLZYLLBP-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is used as a Green chemical. Click here for more information.

Dimethyl carbonate is a unique molecule with versatile chemical reactivity. It is an environmentally benign building block and also a safe substitute for dimethyl sulfate or methyl halides.

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup


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A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia.
Tomishige K, et al.
Catalysis Letters, 58(4), 225-229 (1999)
Catalysis in the production and reactions of dimethyl carbonate, an environmentally benign building block.
Ono Y.
Applied Catalysis A: General, 155(2), 133-166 (1997)

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