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252883

Sigma-Aldrich

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine

Dye content 95 %

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Empirical Formula (Hill Notation):
C48H38N4O4
CAS Number:
Molecular Weight:
734.84
MDL number:
PubChem Substance ID:
NACRES:
NA.47

form

powder or crystals

Quality Level

composition

Dye content, 95%

λmax

424 nm
653 nm (2nd)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

COc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(OC)cc4)c5ccc([nH]5)c(-c6ccc(OC)cc6)c7ccc(n7)c(-c8ccc(OC)cc8)c9ccc2[nH]9

InChI

1S/C48H38N4O4/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31/h5-28,49,52H,1-4H3/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-

InChI key

PJOJZHHAECOAFH-PJEPRTEXSA-N

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This Item
428361247367477567
form

powder or crystals

form

powder or crystals

form

crystalline powder

form

powder

storage temp.

room temp

storage temp.

room temp

storage temp.

room temp

storage temp.

room temp

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

-

composition

Dye content, 95%

composition

Dye content, 85%

composition

-

composition

Dye content, 95%

λmax

424 nm, 653 nm (2nd)

λmax

618.0-624.0 nm in hexane

λmax

415 nm

λmax

421 nm

General description

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine is an achiral porphyrin derivative. It forms chiral supramolecular assemblies via spontaneous symmetry breaking at the air or water interface.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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M Belén Ballatore et al.
European journal of medicinal chemistry, 83, 685-694 (2014-07-11)
A covalently linked porphyrin-fullerene C60 dyad 5 was synthesized by 1,3-dipolar cycloaddition using 5-(4-formylphenyl)-10,15,20-tris[3-(N-ethylcarbazoyl)]porphyrin, N-methylglycine and fullerene C60. Methylation of 5 was used to obtain a cationic dyad 6. Spectroscopic properties were compared in toluene, N,N-dimethylformamide (DMF) and toluene/sodium bis(2-ethylhexyl)sulfosuccinate
Chirality amplification of porphyrin assemblies exclusively constructed from achiral porphyrin derivatives.
Chen P, et al.
ChemPhysChem, 7(11), 2419-2423 (2006)
Maximiliano L Agazzi et al.
Organic & biomolecular chemistry, 18(7), 1449-1461 (2020-02-07)
Chromophore-fullerene C60 hybrids possess interesting properties that enable them to act as heavy atom-free photosensitizers and reactive oxygen species (ROS) producers. Here, two new diketopyrrolopyrrole-C60 conjugates were efficiently synthesized and characterized. The conjugates show broadband absorption in the visible spectral

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