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Sigma-Aldrich

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine cobalt(II)

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Empirical Formula (Hill Notation):
C48H36CoN4O4
CAS Number:
Molecular Weight:
791.76
MDL number:
PubChem Substance ID:
NACRES:
NA.23

form

solid

Quality Level

reaction suitability

reagent type: catalyst
core: cobalt

λmax

417 nm
530 nm (2nd)

SMILES string

COc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(OC)cc4)c5ccc6c(-c7ccc(OC)cc7)c8ccc(n8)c(-c9ccc(OC)cc9)c%10ccc2n%10[Co]n56

InChI

1S/C48H36N4O4.Co/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31;/h5-28H,1-4H3;/q-2;+2/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-;

InChI key

QBCIMRXPMLWVML-NHZJRHMYSA-N

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Application

Starting material in the synthesis of cobalt nitrosyl porphyrins for use in the study of the binding and activation of nitric oxide.

Features and Benefits

Acts as a versatile catalyst during the oxidation of a wide range of organic substrates with dioxygen in the presence of 2-methylpropanal under ambient conditions.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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