90820
Tributyl phosphate
puriss., ≥99.0% (GC)
Synonym(s):
TBP, TBPA
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About This Item
Linear Formula:
(CH3(CH2)3O)3PO
CAS Number:
Molecular Weight:
266.31
Beilstein/REAXYS Number:
1710584
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor density
9.2 (vs air)
Quality Level
vapor pressure
27 mmHg ( 178 °C)
7.3 mmHg ( 150 °C)
grade
puriss.
assay
≥99.0% (GC)
form
liquid
autoignition temp.
770 °F
refractive index
n20/D 1.424 (lit.)
bp
180-183 °C/22 mmHg (lit.)
mp
−79 °C (lit.)
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General description
Tributyl phosphate (TBP) is an organophosphorus compound. TBP is a strong Lewis base and interacts with acids. It is used as a solvent for rare earth extraction and the nuclear fuel cycle. Additionally, TBP is used as a plasticizer for cellulose esters, lacquers, plastics, and vinyl resins
Application
Tributyl phosphate is used as:
- An extractant for monocarboxylic acids(formic, acetic, and propionic) from an aqueous medium.
- An additive to enhance the performance of dye-sensitized solar cells (DSSCs).
- A solvent in combination with ionic liquid[1-butyl-3-methyl imidazolium tetrafluoroborate] for the extraction of phenol and chlorophenols.
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Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk_germany
WGK 2
flash_point_f
293.0 °F - closed cup
flash_point_c
145 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Detailed investigation of lactic acid extraction with tributylphosphate dissolved in dodecane
Labbaci A, et al.
Journal of Chemical and Engineering Data, 55(1), 228-233 (2010)
Extraction of phenol and chlorophenols using ionic liquid [Bmim]+[BF4]- dissolved in tributyl phosphate
Brinda Lakshmi A, et al.
Clean: Soil, Air, Water, 41(4), 349-355 (2013)
Reactive extraction of monocarboxylic acids (formic, acetic, and propionic) using tributyl phosphate in green solvents (cyclopentyl methyl ether and 2-methyltetrahydrofuran
Tu?rk FN, et al.
Journal of Chemical and Engineering Data, 66(1), 130-137 (2020)
Enhanced photovoltaic properties of modified redox electrolyte in dye-sensitized solar cells using tributyl phosphate as additive
Afrooz M and Dehghani H
Journal of Power Sources, 262, 140-146 (2014)
Recep Ali Kumbasar
Journal of hazardous materials, 178(1-3), 875-882 (2010-03-17)
The facilitated extraction of Cr(VI) through an emulsion liquid membrane (ELM) was investigated, using tributyl phosphate (TBP) as mobile carrier. The emulsion liquid membrane phase consists of kerosene as diluent, TBP as carrier, SPAN 80 as surfactant and (NH(4))(2)CO(3) solution
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