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D7766

Sigma-Aldrich

1,5-Diphenylcarbazide

reagent grade

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Synonym(s):
1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide
Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
Molecular Weight:
242.28
Beilstein/REAXYS Number:
752039
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

grade

reagent grade

Quality Level

assay

≥99% (TLC)

form

powder

mp

170-175 °C (lit.)

storage temp.

2-8°C

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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1 of 4

This Item
25922533152N6250
1,5-Diphenylcarbazide reagent grade

D7766

1,5-Diphenylcarbazide

1,5-Diphenylcarbazide ACS reagent

259225

1,5-Diphenylcarbazide

1,5-Diphenylcarbazide reag. Ph. Eur., ≥98.0%, for metal titration

33152

1,5-Diphenylcarbazide

1,3-Dihydroxynaphthalene ≥99%, crystalline

N6250

1,3-Dihydroxynaphthalene

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

powder

form

solid

form

-

form

crystalline

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

room temp

mp

170-175 °C (lit.)

mp

170-175 °C (lit.), 173-176 °C

mp

170-175 °C (lit.)

mp

123-125 °C (lit.), 124-125 °C

grade

reagent grade

grade

ACS reagent

grade

for metal titration

grade

-

General description

1,5-Diphenylcarbazide (DPC) is a colorimetric reagent commonly employed in the determination of trace metals.

Application

1,5-Diphenylcarbazide may be used in the following processes:
  • Quantification of palladium and platinum by spectrophotometry.
  • As a mediator for the functionalization of carbon paste electrodes employed in the estimation of Hg(II) ions by differential pulse voltammetry.
  • Alteration of gold nanoparticles (AuNPs), employed for the detection of chromium (VI) ions via colorimetry.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Photometric and visual detection of Cr (VI) using gold nanoparticles modified with 1, 5-diphenylcarbazide.
Liu, L, et al.
Microchimica Acta, 1-7 (2016)
Spectrophotometric determination of platinum and palladium with 1, 5-diphenylcarbazide.
Brajter K, et al.
Fresenius Journal of Analytical Chemistry, 328(7), 598-598 (1987)
Kinetic method for the determination of trace amounts of copper (II) in water matrices by its catalytic effect on the oxidation of 1, 5-diphenylcarbazide.
Crespo GA, et al.
Analytica Chimica Acta, 539(1), 317-325 (2005)
Hg (II) voltammetry on a 1, 5-diphenylcarbazide containing carbon paste electrode.
Navratilova Z.
Electroanalysis, 3(8), 799-802 (1991)
N Rajesh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 69(2), 612-618 (2007-07-03)
A novel approach has been developed for the solid phase extraction of chromium(VI) based on the adsorption of its diphenylcarbazide complex on a mixture of acid activated montmorillonite (AAM)-silica gel column. The effect of various parameters such as acidity, stability

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