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Key Documents

223530

Sigma-Aldrich

Sodium carbonate

powder, ≥99.5%, ACS reagent

Synonym(s):

Calcined soda, Carbonic acid disodium salt, Soda ash

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About This Item

Linear Formula:
Na2CO3
CAS Number:
Molecular Weight:
105.99
Beilstein/REAXYS Number:
4154566
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

agency

suitable for EPA 300
suitable for SM 2310
suitable for SM 2320
suitable for SM 4500 - NH3

assay

≥99.5%

form

powder

impurities

≤0.005% silica
≤0.01% insolubles

loss

≤1.0% loss on heating

pH

12 (25 °C, 106 g/L)

mp

851 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
phosphate (PO43-): ≤0.001%
sulfur compounds (as SO42-): ≤0.003%

cation traces

Ca: ≤0.03%
Fe: ≤5 ppm
K: ≤0.005%
Mg: ≤0.005%
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O=C(O[Na])O[Na]

InChI

1S/CH2O3.2Na/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

CDBYLPFSWZWCQE-UHFFFAOYSA-L

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General description

Sodium carbonate (soda ash) is an inorganic chemical compound. It is used in the synthesis of chemicals, detergent formulations, flue gas desulfurization, and paper and pulp production.

Application

Sodium carbonate can be used:
  • As a catalyst in the aldol condensation of aldehydes with ketones in the synthesis of chalcone and azachalcone.
  • As a pH stabilizer agent in the synthesis of FeO-NPs (iron oxide nanoparticles) in the presence of cymbopogon citratus as a reducing agent.
  • As a base in the Pd-catalyzed Suzuki coupling reactions.
  • As a base in the transition metal free Suzuki coupling reaction of aryl halides and arylboronic acids to form biaryls using water as a solvent and TBAB (tetrabutylammonium bromide) as a phase-transfer catalyst.

Biochem/physiol Actions

Buffer component, may be used for the removal of peripheral membrane proteins.

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Trousseau described spontaneous, recurrent superficial migratory thrombophlebitis associated with occult cancers, and this was later correlated with disseminated microangiopathy (platelet-rich clots in small blood vessels). Trousseau syndrome often occurs with mucinous adenocarcinomas, which secrete abnormally glycosylated mucins and mucin fragments
Eagleson M.
Concise Encyclopedia Chemistry, 995-995 (1994)
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