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342793

Sigma-Aldrich

Magnesium oxide

≥99% trace metals basis, -325 mesh

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About This Item

Linear Formula:
MgO
CAS Number:
Molecular Weight:
40.30
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.21
assay:
≥99% trace metals basis
form:
powder

Quality Level

assay

≥99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: magnesium

loss

10% loss on ignition, 1000°C (absorbed H2O and CO2)

particle size

-325 mesh

mp

2852 °C (lit.)

SMILES string

O=[Mg]

InChI

1S/Mg.O

InChI key

CPLXHLVBOLITMK-UHFFFAOYSA-N

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General description

Magnesium oxide is a mild basic reagent used in acylations, alkylations, oxidations, reductions, formation of heterocycles, ring-opening of tertiary amines, nitration of aromatic acetals, hydrohalogenation, dehydrohalogenation, carbonylation of organomercurials, and serves as a leaving group to form alkenes.

Application

Magnesium oxide can be used as a catalyst in the:
  • Dehydrogenation of n-octane to synthesize octenes.
  • Solvent-free Knoevenagel condensation of aromatic aldehydes and ethyl cyanoacetate to synthesize electrophilic olefins.

Analysis Note

Purity based on metallic impurity content.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Effect of different catalyst supports on the (n, m) selective growth of single-walled carbon nanotube from Co-Mo catalyst.
Wang B, et al.
J. Mater. Sci., 44(12), 3285-3295 (2009)
Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide.
Ito T and Lunsford JH.
Nature, 721-722 (1985)
Eagleson M.
Concise Encyclopedia Chemistry, 495-495 (1994)
Magnesium oxide-catalysed reaction of carbon dioxide with an epoxide with retention of stereochemistry.
Yano T, et al.
Chemical Communications (Cambridge, England), 12, 1129-1130 (1997)
Benjamin Michen et al.
Environmental science & technology, 47(3), 1526-1533 (2013-01-05)
Ceramic filters, working on the depth filtration principle, are known to improve drinking water quality by removing human pathogenic microorganisms from contaminated water. However, these microfilters show no sufficient barrier for viruses having diameters down to 20 nm. Recently, it

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