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  • A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water.

A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water.

Bioorganic & medicinal chemistry letters (2002-06-28)
Stephen J Connon, Siegfried Blechert
ABSTRACT

The synthesis and olefin metathesis activity in protic solvents of 7, a phosphine-free ruthenium alkylidene bound to a hydrophilic solid support are reported. This heterogeneous catalyst promotes relatively efficient ring closing- and cross-metathesis reactions in both methanol and water. The potential utility of homogeneous catalyst 2 for olefin metathesis in methanol is also demonstrated.

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