710857

塩化鉄(III) 溶液

0.2 M in 2-methyltetrahydrofuran

• 別名: 塩化第二鉄 溶液
• 化学式: FeCl₃
• CAS番号: 7705-08-0
• 分子量: 162.20
• MDL番号: MFCD00011005
• UNSPSCコード: 12161600
• PubChem Substance ID: 329763016
• NACRES: NA.22

特性

• 形状: solution
• 品質水準: 100
• 反応適合性: core: iron; reagent type: catalyst
• 環境により配慮した代替製品の特徴: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 濃度: 0.2 M in 2-methyltetrahydrofuran
• 屈折率: n20/D 1.414
• 密度: 0.868 g/mL at 25 °C
• 環境により配慮した代替製品カテゴリ: , Aligned
• SMILES記法: Cl[Fe](Cl)Cl
• InChI: 1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
• InChI Key: RBTARNINKXHZNM-UHFFFAOYSA-K

詳細

詳細

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl₃ is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.

アプリケーション

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:

• As a mild oxidant for phenolic coupling reaction.
• In dimerizing aryllithiumsand ketone enolates.
• As a mild Lewis acid catalyst to catalyzes ene reactions.
• In Nazarov cyclizations, Michael additions, and acetonation reactions.

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H290,H302,H315,H318
• 注意書き: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
• 補足的ハザード: EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 2
• 引火点(°F): 14.0 °F - closed cup
• 引火点(℃): -10.0 °C - closed cup