804150

SnAP 2,3-Bicyclo-(3,4-Pyr) M Reagent

• 別名: (3R,4R)-tert-butyl 3-amino-4-((tributylstannyl)methoxy) pyrrolidine-1-carboxylate
• 実験式（ヒル表記法）: C₂₂H₄₆N₂O₃Sn
• 分子量: 505.32
• MDL番号: MFCD30491293
• UNSPSCコード: 12352103
• PubChem Substance ID: 329768847
• NACRES: NA.22

特性

• フォーム: liquid
• 品質水準: 100
• 密度: 1.180 at 25 °C
• 官能基: ether
• 保管温度: −20°C
• SMILES記法: CCCC[Sn](CCCC)(CO[C@H]1CN(C(OC(C)(C)C)=O)C[C@@H]1N)CCCC
• InChI: 1S/C10H19N2O3.3C4H9.Sn/c1-10(2,3)15-9(13)12-5-7(11)8(6-12)14-4;3*1-3-4-2;/h7-8H,4-6,11H2,1-3H3;3*1,3-4H2,2H3;/t7-,8-;;;;/m0..../s1
• InChI Key: URTKNAYUDTUPJM-CFACWHMASA-N

詳細

アプリケーション

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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その他情報

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles

安全性情報

• ピクトグラム: GHS06,GHS08,GHS09
• シグナルワード: Danger
• 危険有害性情報: H301,H312,H315,H319,H360FD,H372,H410
• 注意書き: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable