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Phenylmercuric acetate (PMA) can react with a palladium salt such as palladium acetate to form an arylpalladium salt in situ, which then reacts with primary or secondary allylic alcohols to produce 3-aryl aldehydes. It can also be used in the multi-step synthesis of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl thiol via Floyd′s pathway.
シグナルワード
Danger
危険有害性情報
危険有害性の分類
Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
ターゲットの組織
Kidney,Central nervous system
保管分類コード
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
引火点(°F)
Not applicable
引火点(℃)
Not applicable
個人用保護具 (PPE)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
毒物及び劇物取締法
毒物
PRTR
第一種指定化学物質
労働安全衛生法名称等を表示すべき危険物及び有害物
名称等を表示すべき危険物及び有害物
労働安全衛生法名称等を通知すべき危険物及び有害物
名称等を通知すべき危険物及び有害物
Jan Code
P27127-100G:4548173206097
P27127-BULK:
P27127-25G:4548173206103
P27127-VAR:
Synthesis of aromatic and indole alpha-glucosinolates.
Vo Quan V, et al.
Carbohydrate Research, 455, 45-53 (2018)
The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones.
Heck R F, et al.
Journal of the American Chemical Society, 90(20), 5526-5531 (1968)
S K Ghosh et al.
Journal of applied microbiology, 102(2), 375-383 (2007-01-24)
Mercury compounds are highly toxic to all types of living cells. Isolated yeast strains of Rhodotorula rubra showed high and low resistance pattern towards mercury and organomercurial compounds. To investigate the basis of differential sensitivity of these two types of
Harry J Beaulieu et al.
Journal of occupational and environmental hygiene, 5(6), 360-366 (2008-03-28)
Phenyl mercuric acetate (PMA) historically has been used as a catalyst in polyurethane systems. In the 1950s-1970s, PMA was used as a catalyst in the 3M Tartan brand polyurethane flexible floors that were installed commonly in school gymnasiums. Mercury vapor
Lilla Landeck et al.
International journal of dermatology, 50(7), 806-810 (2011-06-28)
Some authors have claimed a decreased cell-mediated immunity among atopic individuals, which would lead to observations of decreased rates of allergic contact dermatitis (ACD). The purpose of our study was to investigate contact sensitization patterns in atopic subjects compared with
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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