74011
(±)-Diclofop
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
別名:
(RS)-2-[4-(2,4-Dichlorophenoxy)phenoxy]propionic acid
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About This Item
実験式（ヒル表記法）:
C15H12Cl2O4
CAS番号:
分子量:
327.16
Beilstein:
2338390
MDL番号:
UNSPSCコード:
41116107
NACRES:
NA.24
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グレード
certified reference material
TraceCERT®
品質水準
製品種目
TraceCERT®
シェルフライフ
limited shelf life, expiry date on the label
メーカー／製品名
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
フォーマット
neat
保管温度
2-8°C
SMILES記法
CC(Oc1ccc(Oc2ccc(Cl)cc2Cl)cc1)C(O)=O
InChI
1S/C15H12Cl2O4/c1-9(15(18)19)20-11-3-5-12(6-4-11)21-14-7-2-10(16)8-13(14)17/h2-9H,1H3,(H,18,19)
InChI Key
OOLBCHYXZDXLDS-UHFFFAOYSA-N
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詳細
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
(+/–)-Diclofop is a chiral herbicide that belongs to the chemical class of chiral aryloxyphenoxypropionate compounds. The actual herbicidal active ingredient― carboxylic acid, is released after application through hydrolysis of the ester. It is absorbed mainly through leaves and inhibits the biosynthesis of fatty acids by suppressing the activity of acetyl CoA carboxylase (ACCase). It is used for the post-emergence control of wild oats, wild millets, and other annual grass weeds commonly occurring in wheat, barley, rye, red fescue, and broad-leaved crops.
It was included on 1st June 2011 in Annex I of Directive 91/414/EEC by the European Commission Directive 2011/45/EU. It is authorized for use under EC Regulation No 1107/2009, as per the Commission Implementing Regulation (EU) No 540/2011, however it is a candidate for substitution.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
(+/–)-Diclofop is a chiral herbicide that belongs to the chemical class of chiral aryloxyphenoxypropionate compounds. The actual herbicidal active ingredient― carboxylic acid, is released after application through hydrolysis of the ester. It is absorbed mainly through leaves and inhibits the biosynthesis of fatty acids by suppressing the activity of acetyl CoA carboxylase (ACCase). It is used for the post-emergence control of wild oats, wild millets, and other annual grass weeds commonly occurring in wheat, barley, rye, red fescue, and broad-leaved crops.
It was included on 1st June 2011 in Annex I of Directive 91/414/EEC by the European Commission Directive 2011/45/EU. It is authorized for use under EC Regulation No 1107/2009, as per the Commission Implementing Regulation (EU) No 540/2011, however it is a candidate for substitution.
アプリケーション
It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
The (+/–)-Diclofop CRM can also be used as following:
The (+/–)-Diclofop CRM can also be used as following:
- To evaluate the likely enantioselective oxidative stress produced in Microcystis aeruginosa by diclofop acid
- For analyzing the phytotoxic effects of diclofop acid enantiomers on the plant Arabidopsis thaliana
- To study the enantioselective toxicity of diclofop acid on the non-target rice Xiushui 63 seedlings
- In the chiral separation of diclofop-acid using one- and two- dimensional HPLC methods
- To determine the enantioselective toxicity and degradation of diclofop in three algal cultures
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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
法的情報
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
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シグナルワード
Warning
危険有害性情報
危険有害性の分類
Acute Tox. 4 Oral
保管分類コード
11 - Combustible Solids
WGK
WGK 3
引火点(°F)
Not applicable
引火点(℃)
Not applicable
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Jan Code
74011-50MG:
74011-BULK:
74011-VAR:
最新バージョンのいずれかを選択してください：
Xiyun Cai et al.
Journal of agricultural and food chemistry, 56(6), 2139-2146 (2008-03-06)
Aryloxyphenoxypropanoates are a class of chiral herbicides. They have a pair of enantiomers, only the R(+) form of which is herbicidally active. Diclofop, the model compound of these herbicides, is commercialized as the racemate of the ester form, diclofop-methyl, consisting
Jing Ye et al.
Aquatic toxicology (Amsterdam, Netherlands), 146, 12-19 (2013-11-19)
Enantioselective oxidative stress and toxin release from Microcystis aeruginosa after exposure to the chiral herbicide diclofop acid were investigated. Racemic diclofop acid, R-diclofop acid and S-diclofop acid induced reactive oxygen species (ROS) generation, increased the concentration of malondialdehyde (MDA), enhanced
Jing Ye et al.
Bulletin of environmental contamination and toxicology, 83(1), 85-91 (2009-05-20)
In this study, the acute toxicity (72-h EC50 values) of chiral diclofop acid towards rice Xiushui 63 seedlings and its effects on the Hill reaction activities of chloroplasts were determined. Significant differences were observed between the two enantiomers in 72-h
Qiong Zhang et al.
Environmental science & technology, 46(15), 8405-8412 (2012-07-10)
Diclofop-methyl (DM) is a widely used chiral herbicide, which rapidly hydrolyzes to its major metabolite diclofop acid (DC) after application. With a carbon chiral center, DC not only is an important ingredient of herbicidal activity, but also has a long
Xiyun Cai et al.
Journal of agricultural and food chemistry, 56(6), 2139-2146 (2008-03-06)
Aryloxyphenoxypropanoates are a class of chiral herbicides. They have a pair of enantiomers, only the R(+) form of which is herbicidally active. Diclofop, the model compound of these herbicides, is commercialized as the racemate of the ester form, diclofop-methyl, consisting
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