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Merck
모든 사진(1)

주요 문서

103543

Sigma-Aldrich

4-Nitroanisole

97%

동의어(들):

1-Methoxy-4-nitrobenzene

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About This Item

Linear Formula:
O2NC6H4OCH3
CAS Number:
Molecular Weight:
153.14
Beilstein:
1865361
EC Number:
MDL number:
UNSPSC 코드:
12352100
eCl@ss:
39032065
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

97%

형태

solid

density

1.233 g/mL at 25 °C (lit.)

작용기

nitro

SMILES string

COc1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

InChI key

BNUHAJGCKIQFGE-UHFFFAOYSA-N

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관련 카테고리

일반 설명

4-Nitroanisole undergoes photochemical nucleophilic aromatic substitution by hydroxide ion to form 4-methoxyphenol and 4-nitrophenol.

애플리케이션

4-Nitroanisole was used as probe to determine Π* of Kamlet-Taft solvent parameters and high pressure and supercritical water in the temperature range of 16-420 °C. 4-Nitroanisole was used as carbon and energy supplement for the isolation of Rhodococcus strains.

생화학적/생리학적 작용

4-Nitroanisole is O-demethylated to 4-nitrophenol by human liver microsomes.

픽토그램

Health hazard

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Aquatic Chronic 3 - Carc. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point (°F)

266.0 °F - closed cup

Flash Point (°C)

130 °C - closed cup

개인 보호 장비

Eyeshields, Gloves


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문서 라이브러리 방문

Vadim Samoilov et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-15)
In this study approaches for chemical conversions of the renewable compounds 1,2-propanediol (1,2-PD) and 2,3-butanediol (2,3-BD) that yield the corresponding cyclic ketals and glycol ethers have been investigated experimentally. The characterization of the obtained products as potential green solvents and
Petr Klán et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(12), 1012-1016 (2003-03-29)
A temperature-sensitive photochemical nucleophilic aromatic substitution on 4-nitroanisole by a hydroxide ion in homogeneous solutions, in a two-phase system under phase-transfer catalysis conditions, and in the microwave field is reported. It was found that reaction regioselectivity dramatically changes with temperature
D J Sequeira et al.
Biochimica et biophysica acta, 1207(2), 179-186 (1994-08-17)
The goal of this study was to examine the effect of duration of ethylbenzene exposure on cytochrome P-450-dependent activities. Male rats were treated with ethylbenzene by intraperitoneal injection for either 1 or 3 days, and microsomal preparations were examined for
Andrea Ciani et al.
Environmental science & technology, 39(17), 6712-6720 (2005-09-30)
Photodegradation is a key process in governing the residence time and fate of many agrochemicals in top soils. However, the basic knowledge of the photolytic transformation reactions of organic chemicals on soil surfaces is still very poor, particularly regarding the
A Schäfer et al.
Biodegradation, 7(3), 249-255 (1996-06-01)
Two Rhodococcus strains, R. opacus strain AS2 and R. erythropolis strain AS3, that were able to use 4-nitroanisole as the sole source of carbon and energy, were isolated from environmental samples. The first step of the degradation involved the O-demethylation

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