추천 제품
Grade
produced by Wacker Chemie AG, Burghausen, Germany
Quality Level
분석
≥99.0% (GC)
refractive index
n20/D 1.415 (lit.)
bp
128-130 °C (lit.)
density
1.094 g/mL at 25 °C (lit.)
SMILES string
COC(CCl)OC
InChI
1S/C4H9ClO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3
InChI key
CRZJPEIBPQWDGJ-UHFFFAOYSA-N
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일반 설명
Chloroacetaldehyde dimethyl acetal is a clear, colorless liquid. It reacts with hydroxythiol to form hydroxy acetal.
애플리케이션
Chloroacetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- 2-(chloromethyl)-4,7-dethyl-1,3-dioxepane
- 2-(chloromethyl)-5,6-benzo-1,3-dioxepane
- ketene dimethyl acetal
Chloroacetaldehyde dimethyl acetal was used to investigate the enzymes used for activation and transformation of vinyl chloride. It was also used for introducing O-(2,2-dimethoxyethyl) groups into amylose, dextran, and a linear (1→3)-β-D-glucan. Chloroacetaldehyde dimethyl acetal was utilised in the synthesis of ethoxyacetylide.
기타 정보
prices for bulk quantities on request
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
84.2 °F - closed cup
Flash Point (°C)
29 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Simple enols. 3. Stereochemistry of simple enols in solution.
The Journal of Organic Chemistry, 49(2), 255-257 (1984)
Activation of vinyl chloride to covalently bound metabolites: roles of 2-chloroethylene oxide and 2-chloroacetaldehyde.
Biochemistry, 18(23), 5177-5182 (1979-11-13)
Recent trends in the synthesis of carbazoles: an update.
Tetrahedron, 68(31), 6099-6121 (2012)
Coupling of polysaccharides activated by means of chloroacetaldehyde dimethyl acetal to amines or proteins by reductive amination.
Carbohydrate Research, 148(1), 101-107 (1986)
Free radical ring-opening polymerization of 4, 7-dimethyl-2-methylene-1, 3-dioxepane and 5, 6-benzo-2-methylene-1, 3-dioxepane.
Macromolecules, 15(3), 711-714 (1982)
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