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Merck
모든 사진(1)

주요 문서

10906

Sigma-Aldrich

Chloroacetaldehyde dimethyl acetal

produced by Wacker Chemie AG, Burghausen, Germany, ≥99.0% (GC)

동의어(들):

CADMA, 2-Chloro-1,1-dimethoxyethane, Dimethyl chloroacetal

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About This Item

Linear Formula:
ClCH2CH(OCH3)2
CAS Number:
Molecular Weight:
124.57
Beilstein:
1733700
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
분석:
≥99.0% (GC)

Grade

produced by Wacker Chemie AG, Burghausen, Germany

Quality Level

분석

≥99.0% (GC)

refractive index

n20/D 1.415 (lit.)

bp

128-130 °C (lit.)

density

1.094 g/mL at 25 °C (lit.)

SMILES string

COC(CCl)OC

InChI

1S/C4H9ClO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3

InChI key

CRZJPEIBPQWDGJ-UHFFFAOYSA-N

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일반 설명

Chloroacetaldehyde dimethyl acetal is a clear, colorless liquid. It reacts with hydroxythiol to form hydroxy acetal.

애플리케이션

Chloroacetaldehyde dimethyl acetal can be used as a reactant to synthesize:
  • 2-(chloromethyl)-4,7-dethyl-1,3-dioxepane
  • 2-(chloromethyl)-5,6-benzo-1,3-dioxepane
  • ketene dimethyl acetal

Chloroacetaldehyde dimethyl acetal was used to investigate the enzymes used for activation and transformation of vinyl chloride. It was also used for introducing O-(2,2-dimethoxyethyl) groups into amylose, dextran, and a linear (1→3)-β-D-glucan. Chloroacetaldehyde dimethyl acetal was utilised in the synthesis of ethoxyacetylide.

기타 정보

prices for bulk quantities on request

픽토그램

FlameExclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point (°F)

84.2 °F - closed cup

Flash Point (°C)

29 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Simple enols. 3. Stereochemistry of simple enols in solution.
Capon B
The Journal of Organic Chemistry, 49(2), 255-257 (1984)
Activation of vinyl chloride to covalently bound metabolites: roles of 2-chloroethylene oxide and 2-chloroacetaldehyde.
F P Guengerich et al.
Biochemistry, 18(23), 5177-5182 (1979-11-13)
Recent trends in the synthesis of carbazoles: an update.
Tetrahedron, 68(31), 6099-6121 (2012)
Coupling of polysaccharides activated by means of chloroacetaldehyde dimethyl acetal to amines or proteins by reductive amination.
B?gwald J, et al.
Carbohydrate Research, 148(1), 101-107 (1986)
Free radical ring-opening polymerization of 4, 7-dimethyl-2-methylene-1, 3-dioxepane and 5, 6-benzo-2-methylene-1, 3-dioxepane.
Bailey WJ
Macromolecules, 15(3), 711-714 (1982)

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