148083
1,1,1-Tris(hydroxymethyl)propane
97%
동의어(들):
2-Ethyl-2-hydroxymethyl-1,3-propanediol, Trimethylolpropane
로그인조직 및 계약 가격 보기
모든 사진(2)
About This Item
Linear Formula:
CH3CH2C(CH2OH)3
CAS Number:
Molecular Weight:
134.17
Beilstein:
1698309
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
vapor density
4.8 (vs air)
vapor pressure
<1 mmHg ( 20 °C)
분석
97%
형태
(Powder or Crystals or Granules or Chunks)
autoignition temp.
1301 °F
bp
159-161 °C/2 mmHg (lit.)
mp
56-58 °C (lit.)
작용기
hydroxyl
SMILES string
CCC(CO)(CO)CO
InChI
1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3
InChI key
ZJCCRDAZUWHFQH-UHFFFAOYSA-N
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애플리케이션
1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Repr. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point (°F)
356.0 °F - Cleveland open cup
Flash Point (°C)
180 °C - Cleveland open cup
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
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