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애플리케이션
2-Bromothiazole was used to N-arylate 5- and 7-azaindoles. 2-Bromothiazole was also used as starting reagent in the synthesis of:
- 2-cyanothiazole via cpper-catalyzed cyanation
- 2,4,5-trisubstituted thiazoles
- novel electron-deficient fused pyrrolo[3,2-d:4,5-d′]bisthiazole
- 3-(2′-thiazoyl)indoles
Storage Class Code
12 - Non Combustible Liquids
WGK
WGK 3
Flash Point (°F)
closed cup - does not flash
Flash Point (°C)
closed cup - does not flash
개인 보호 장비
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
이미 열람한 고객
Organic letters, 12(23), 5478-5481 (2010-11-12)
The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d']bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and
Synthesis of camalexin and related phytoalexins.
Tetrahedron, 48(14), 2919-2924 (1992)
Tetrahedron Letters, 48, 4831-4831 (2007)
Synlett, 555-555 (2007)
The Journal of organic chemistry, 76(16), 6972-6978 (2011-07-09)
A general method for the synthesis of 2,4,5-trisubstituted thiazoles has been developed. Starting from commercially available 2-bromothiazole, successive metalations using TMPMgCl·LiCl or TMP(2)Zn·2MgCl(2)·2LiCl lead to the corresponding magnesated or zincated thiazoles which readily react with various electrophiles providing highly functionalized
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