186651

18-Crown-6

99%

• 동의어(들): 1,4,7,10,13,16-Hexaoxacyclooctadecane
• 실험식(Hill 표기법): C₁₂H₂₄O₆
• CAS Number: 17455-13-9
• Molecular Weight: 264.32
• Beilstein: 1619616
• EC Number: 241-473-5
• MDL number: MFCD00005113
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24851233
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 99%
• 양식: solid
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 42-45 °C (lit.)
• 작용기: ether
• 환경친화적 대안 카테고리: , Aligned
• SMILES string: O1CCOCCOCCOCCOCCOCC1
• InChI: 1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
• InChI key: XEZNGIUYQVAUSS-UHFFFAOYSA-N

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

18-Crown-6 is the simplest crown ether that can be prepared by reacting triethylene glycol with triethylene glycol dichloride in the presence of potassium hydroxide as base.

애플리케이션

18-Crown-6 may be used to catalyze the N-alkylation of heterocyclic compounds and allylation of functionalized aldehydes.

Additive for greener etherification using KF-alumina.

Additive for greener etherification using KF-alumina.

Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6

Can be useful as phase-transfer catalysts.

Phase-transfer catalyst used in a chemoselective reduction of fused tetrazoles with NaBH₄ and potassium hydroxide.

기타 정보

Macrocyclic polyethers with repeating (-CH₂CH₂O) units. The compounds are ionophoric (form stable complexes with cations).

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302
• 예방조치 성명서: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves