205273

Titanium(IV) isopropoxide

97%

• 동의어(들): TTIP, Tetraisopropyl orthotitanate
• Linear Formula: Ti[OCH(CH₃)₂]₄
• CAS Number: 546-68-9
• Molecular Weight: 284.22
• Beilstein: 3679474
• EC Number: 208-909-6
• MDL number: MFCD00008871
• UNSPSC 코드: 12352106
• PubChem Substance ID: 24852318
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 97%
• 양식: liquid
• 반응 적합성: core: titanium; reagent type: catalyst
• refractive index: n20/D 1.464 (lit.)
• bp: 232 °C (lit.)
• mp: 14-17 °C (lit.)
• density: 0.96 g/mL at 20 °C (lit.)
• SMILES string: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
• InChI: 1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

설명

일반 설명

Titanium(IV) isopropoxide is a titanium-based coordination compound, commonly used in the asymmetric Sharpless epoxidation reaction of allylic alcohols. It is also used as a catalyst in Kulinkovich reaction for the synthesis of cyclopropanes.[1][2][3]

애플리케이션

Commonly used as a precursor for the preparation of Titania (TiO₂)[4][5]

Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO₂ nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

포장

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

법적 정보

Product of Dorf Ketal

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H319,H336
• 예방조치 성명서: P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
• 표적 기관: Central nervous system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point (°F): 105.8 °F - Pensky-Martens closed cup
• Flash Point (°C): 41 °C - Pensky-Martens closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter