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Merck
모든 사진(3)

주요 문서

205761

Sigma-Aldrich

Palladium(II) nitrate hydrate

동의어(들):

Palladium dinitrate hydrate, Palladium nitrate hydrate, Palladous nitrate hydrate

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About This Item

Linear Formula:
Pd(NO3)2·xH2O
CAS Number:
Molecular Weight:
230.43 (anhydrous basis)
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

형태

powder and chunks

Quality Level

구성

Degree of hydration, ~2

반응 적합성

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES string

O.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.H2O.Pd/c2*2-1(3)4;;/h;;1H2;/q2*-1;;+2

InChI key

DTZRLFJKQHIVQA-UHFFFAOYSA-N

애플리케이션

Reactant for:
  • Preparation of platinum-palladium/carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells
  • Synthesis of Cu-Pd alloy thin films on Ti substrates by co-electrodeposition of Pd and Cu from nitrate-base electrolytic baths
  • Preparation of palladium catalyst supported on vertically aligned multi-walled carbon nanotubes for microwave-assisted Heck reactions of p-iodonitrobenzene with styrene and Et acrylate
  • Preparation of a sinter-resistant Pd/SiO2 nanocatalyst
  • Preparation of di-phenyl sulfide-modified Pd/TiO2 catalysts for acetylene hydrogenation
  • Synthesis of alumina-supported palladium catalysts active for the gas phase hydrogenation of crotonaldehyde
Catalyst for alkene nitration to glycol dinitrates; also used as a precursor to supported Pd catalysts.

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - Ox. Sol. 1 - Skin Corr. 1B

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Hatice Gamze Soğukömeroğulları et al.
Journal of hazardous materials, 369, 96-107 (2019-02-19)
We reported the improved catalytic property of Pd (0) nanoparticles decorated on amine-functionalized graphene nanosheets (Pd/GNS-NH2) for the hydrogenation of nitrophenol derivatives in the presence of NaBH4 at moderate conditions. Pd/GNS-NH2 nanocatalyst was synthesized by the deposition-reduction method. Sundry techniques

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