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애플리케이션
Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (−)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
포장
기타 정보
Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
표적 기관
Central nervous system, Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (−)-phenserine
Journal of the American Chemical Society, 126(43), 14043-14053 (2004)
Enantioselective synthesis of stephacidin B.
Journal of the American Chemical Society, 127(15), 5342-5344 (2005)
Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents.
Angewandte Chemie (International Edition in English), 39(9), 1602-1604 (2000)
Functional group tolerant Kumada- Corriu- Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles: Catalysis by a nickel pincer complex permits the coupling of functionalized Grignard reagents.
Journal of the American Chemical Society, 131(28), 9756-9766 (2009)
Electrolyte solutions with a wide electrochemical window for rechargeable magnesium batteries.
Journal of the Electrochemical Society, 155(2), A103-A109 (2008)
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