703559

Lanthanum(III) chloride bis(lithium chloride) complex solution

0.6 M in THF

• 동의어(들): Lanthanum trichloride lithium chloride complex
• Linear Formula: LaCl₃ · 2LiCl
• CAS Number: 405204-22-0
• Molecular Weight: 330.05
• UNSPSC 코드: 12352106
• PubChem Substance ID: 329762049
• NACRES: NA.22

속성

• 형태: liquid
• Quality Level: 100
• 반응 적합성: reagent type: catalyst; core: lanthanum
• 농도: 0.6 M in THF; 16 % (w/w)
• density: 1.05 g/mL at 25 °C
• SMILES string: [Li]Cl.[Li]Cl.Cl[La](Cl)Cl
• InChI: 1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
• InChI key: YSKOYVQYUJUXCN-UHFFFAOYSA-I

설명

애플리케이션

Selective 1,2-Additions with LaCl3•2LiCl

• Mediates Grignard additions
• Reagent for metal exchange reactions
• Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines

법적 정보

Product of Albemarle US Inc

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H290,H302,H317,H318,H335,H336,H351,H412
• 예방조치 성명서: P210 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point (°F): 62.6 °F
• Flash Point (°C): 17 °C
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter