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애플리케이션
2-Mesitylmagnesium bromide is a Grignard reagent generally used to synthesize stable aromatic radical species such as dibenzoheptazethrene, diindenoanthracene, teranthene and dimesitylindeno[2,1-a]fluorene by kinetically blocking reactive molecular sites. It is also used in a variety of aromatic cross-coupling reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
표적 기관
Central nervous system, Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17.0 °C - closed cup
가장 최신 버전 중 하나를 선택하세요:
이미 열람한 고객
Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals.
Nature Chemistry, 8(8), 753-753 (2016)
Indeno [2, 1-a] fluorene: An Air-Stable ortho-Quinodimethane Derivative.
Angewandte Chemie (International Edition in English), 123(30), 7038-7042 (2011)
Highly selective biaryl cross-coupling reactions between aryl halides and aryl Grignard reagents: a new catalyst combination of N-heterocyclic carbenes and iron, cobalt, and nickel fluorides.
Journal of the American Chemical Society, 131(33), 11949-11963 (2009)
Synthesis and characterization of teranthene: a singlet biradical polycyclic aromatic hydrocarbon having Kekule structures.
Journal of the American Chemical Society, 132(32), 11021-11023 (2010)
Iron-catalyzed selective biaryl coupling: Remarkable suppression of homocoupling by the fluoride anion.
Journal of the American Chemical Society, 129(32), 9844-9845 (2007)
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