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모든 사진(3)

Key Documents

227749

Sigma-Aldrich

Bis(acetylacetonato)dioxomolybdenum(VI)

동의어(들):

MoO2(acac)2, Molybdenum diacetylacetonate dioxide, Molybdenum dioxide bis(acetylacetonate), Molybdenum dioxydiacetylacetonate, Molybdenyl acetylacetonate

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About This Item

Linear Formula:
[CH3COCH=C(O-)CH3]2MoO2
CAS Number:
Molecular Weight:
326.15
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

형태

powder

반응 적합성

core: molybdenum
reagent type: catalyst

mp

184 °C (dec.) (lit.)

저장 온도

2-8°C

SMILES string

CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;

InChI key

SKMUJBBRXZPAJY-VGKOASNMSA-L

일반 설명

Bis(acetylacetonato)dioxomolybdenum(VI) is used as a starting material and catalyst for oxidative transformation reactions.

애플리케이션

Bis(acetylacetonato)dioxomolybdenum(VI) can be used:
  • As a starting material to synthesize dioxomolybdenum(VI) Schiff base complexes, applicable as catalysts in the oxidation of alcohols using H2O2.
  • To prepare graphene oxide supported heterogeneous molybdenum catalysts for epoxidation of olefins.
  • As a catalyst in the etherification and thio-etherification reactions of thiols and alcohols.

픽토그램

Health hazardExclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

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문서 라이브러리 방문

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Synthesis, structures, electrochemical studies and antioxidant activities of cis-dioxomolybdenum (VI) complexes of the new bisthiocarbohydrazones
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Dinuclear and polynuclear dioxomolybdenum (VI) Schiff base complexes: synthesis, structural elucidation, spectroscopic characterization, electrochemistry and catalytic property
Ngan NK, et al.
Polyhedron, 33(1), 235-251 (2012)
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