256021

(Trimethylsilyl)methylmagnesium chloride solution

1.0 M in diethyl ether

• 동의어(들): (Trimethylsilyl)methyl magnesium chloride, Chloro(trimethylsilylmethyl)magnesium
• Linear Formula: (CH₃)₃SiCH₂MgCl
• CAS Number: 13170-43-9
• Molecular Weight: 146.97
• Beilstein: 3587255
• MDL number: MFCD00009916
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24855503
• NACRES: NA.22

속성

• Quality Level: 100
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 1.0 M in diethyl ether
• density: 0.777 g/mL at 25 °C
• SMILES string: C[Si](C)(C)C[Mg]Cl
• InChI: 1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1
• InChI key: NAQATMJWCJCHOZ-UHFFFAOYSA-M

설명

애플리케이션

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H314,H336
• 예방조치 성명서: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system
• 보충제 위험성: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): -40.0 °F - closed cup
• Flash Point (°C): -40 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter