373710

Molybdenum(VI) dichloride dioxide

• 동의어(들): Dichlorodioxomolybdenum
• Linear Formula: MoO₂Cl₂
• CAS Number: 13637-68-8
• Molecular Weight: 198.84
• MDL number: MFCD00014225
• UNSPSC 코드: 12352302
• PubChem Substance ID: 24863255
• NACRES: NA.23

속성

• 형태: flakes
• 농도: 34.4-36.9% chloride (silver nitrate titration)
• density: 3.31 g/mL at 25 °C (lit.)
• 응용 분야: battery manufacturing
• SMILES string: Cl[Mo](Cl)(=O)=O
• InChI: 1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2
• InChI key: JCFNAADCQWXIJD-UHFFFAOYSA-L

설명

일반 설명

Molybdenum(VI) dichloride dioxide is an oxo-halide of molybdenum widely used as a catalyst for various organic transformations. It is an oxo-transfer catalyst that has the ability to promote oxidation as well as reduction reactions. It can also be used as a chemical vapor deposition(CVD) precursor to synthesize various Mo-based nanomaterials.

애플리케이션

Molybdenum(VI) dichloride dioxide can be used as a catalyst:

• For thioacetalization of heterocyclic, aromatic, and aliphatic compounds.
• To synthesize mono-, di-, tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates.
• For stereospecific deoxygenation of epoxides to alkenes.
• For the synthesis of dihydropyrimidinone/thione and polyhydroquinoline derivatives via a Biginelli and Hantzsch reaction.

It can also be used as a precursor to synthesize MoO₂ nanoparticles.

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges