모든 사진(1)

문서

248940

(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Name: (<I>S</I>)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Brand: ALDRICH

97%

동의어(들):

(S)-(+)-1,1′-Binaphthalene-2,2′-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

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모든 사진(1)

About This Item

실험식(Hill 표기법):

C₂₀H₁₃O₄P

CAS Number:

35193-64-7

Molecular Weight:

348.29

Beilstein:

4787775

MDL number:

MFCD00010045

UNSPSC 코드:

12352005

PubChem Substance ID:

24854963

NACRES:

NA.22

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

248932

(R)-(−)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

689890

(R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

292966

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

689785

(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

C2107

(1S)-(+)-10-Camphorsulfonic acid

Sigma-Aldrich

402885

p-Toluenesulfonic acid monohydrate

Sigma-Aldrich

695718

(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

246948

(R)-(+)-1,1′-Bi(2-naphthol)

Sigma-Aldrich

382426

(R)-(+)-1,1′-Binaphthyl-2,2′-diamine

Sigma-Aldrich

246956

(S)-(−)-1,1′-Bi(2-naphthol)

Quality Level

100

분석

97%

형태

solid

광학 활성

[α]22/D +595°, c = 1.35 in methanol

SMILES string

OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45

InChI

1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)

InChI key

JEHUZVBIUCAMRZ-UHFFFAOYSA-N

애플리케이션

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

애플리케이션

제품 번호

설명

가격

G004718

HPLC Analysis of 1,1′-Binaphthyl-2,2′-diyl Hydrogenphosphate Enantiomers on Astec^® (R,R) P-CAP^™, application for HPLC

픽토그램

GHS07

신호어

Warning

유해 및 위험 성명서

H315

예방조치 성명서

P302 + P352

Hazard Classifications

Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)

시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 6

1 of 6

Sigma-Aldrich

689785

(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

695718

(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

374121

(1S)-(+)-3-Bromocamphor-10-sulfonic acid hydrate

Sigma-Aldrich

688320

(S)-VAPOL hydrogenphosphate

Sigma-Aldrich

448427

(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide

Sigma-Aldrich

717738

(S)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.

Masahiro Yamanaka et al.

Journal of the American Chemical Society, 129(21), 6756-6764 (2007-05-05)

Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino esters with good diastereoselectivity in favor of the syn isomer and high

Comparative study on the enantiomer separation of 1,1'-binaphthyl-2,2'diyl hydrogenphosphate and 1,1'-bi-2-naphthol by liquid chromatography and capillary electrophoresis using single and combined chiral selector systems.

Anna Bielejewska et al.

Journal of chromatography. A, 977(2), 225-237 (2002-11-29)

The chiral recognition ability of single and dual selectors, that were used as additives, have been investigated by HPLC and CE. Native beta- and gamma-cyclodextrins, permethylated beta-cyclodextrin, hydroxypropyl-beta-cyclodextrin, cholic acid and taurodeoxycholic acid sodium salts were applied as chiral selectors

Chiral selectivity of guanosine media in capillary electrophoresis.

Yingying Dong et al.

Electrophoresis, 32(13), 1735-1741 (2011-06-28)

Gels formed by self-association of monomeric guanosine compounds join numerous other agents such as cyclodextrins, crown ethers, chiral surfactants, antibiotics, proteins, and polysaccharides for chiral separations. Guanosine gels (G-gels) are self-assembled networks of hydrogen-bonded tetrads formed by guanosine nucleotides and

Enantioseparation of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis.

B Chankvetadze et al.

Chirality, 10(1-2), 134-139 (1998-02-21)

Twelve different disaccharides and a series of noncyclic malto- and cello-oligosaccharides were used as chiral selectors in capillary electrophoresis (CE). Most saccharides resolved the enantiomers of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (BDHP) depending on the type (alpha or beta) and position

Delta-cyclodextrin as novel chiral probe for enantiomeric separation by electromigration methods.

Dorothee Wistuba et al.

Electrophoresis, 27(21), 4359-4363 (2006-10-06)

Native delta-CD has been employed as chiral selector in CE and MEKC. To investigate the potential of the enantiodiscriminating properties of delta-CD, negatively charged 5-dimethylamino-1-naphthalene-sulfonyl (dansyl)-, 2,4-dinitrophenyl (DNP)- and FMOC-derivatives of several amino acids, 1,1'-binaphthyl-2,2'-diylhydrogenphosphate, flavanones and three positively charged

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Chiral Phosphoric Acids: Versatile Organocatalysts with Expanding Applications

TRIP and TiPSY Chiral Phosphoric Acid Catalysts

Chromatograms

HPLC Analysis of 1,1′-Binaphthyl-2,2′-diyl Hydrogenphosphate Enantiomers on Astec^® (R,R) P-CAP^™

application for HPLC

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문서

(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate