404411

(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

98%

• 동의어(들): (R,R)-Jacobsen’s ligand
• Linear Formula: [[(CH₃)₃C]₂C₆H₂-2-(OH)CH=N]₂C₆H₁₀
• CAS Number: 135616-40-9
• Molecular Weight: 546.83
• Beilstein: 5464823
• MDL number: MFCD00191800
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24865244
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 98%
• 형태: solid
• 광학 활성: [α]20/D −315±15°, c = 1 in methylene chloride
• mp: 205-207 °C (lit.)
• 작용기: imine
• SMILES string: CC(C)(C)c1cc(\C=N\[C@@H]2CCCC[C@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C
• InChI: 1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m1/s1
• InChI key: FYNXDGNCEBQLGC-LQWPWIHBSA-N

설명

애플리케이션

Amylases from Aspergillus oryzae are used to prevent staling in the baking industry, clarify haze from fruit juices and alcoholic beverages, and produce glucose and maltose syrup products.

Versatile ligand for asymmetric catalysis. Ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.

Lipases are used industrially for the resolution of chiral compounds and the transesterification production of biodiesel.

생화학적/생리학적 작용

α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sugars.

Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids.

법적 정보

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves