추천 제품
vapor pressure
7 mmHg ( 21 °C)
Quality Level
구성
Pt, ~2%
반응 적합성
core: platinum
reagent type: catalyst
농도
in xylene
bp
138 °C
mp
12-13 °C
density
0.855 g/mL at 25 °C
SMILES string
[Pt].C[Si](C)(O[Si](C)(C)C=C)C=C
InChI
1S/C8H18OSi2.Pt/c1-7-10(3,4)9-11(5,6)8-2;/h7-8H,1-2H2,3-6H3;
InChI key
RCNRJBWHLARWRP-UHFFFAOYSA-N
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일반 설명
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions.
애플리케이션
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution is a powerful hydrosilylation catalyst for the preparation of trans-β-silanes.
It has also been used in the reduction of carboxamides to amines.
It has also been used in the reduction of carboxamides to amines.
신호어
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3
표적 기관
Central nervous system,Liver,Kidney, Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
77.0 °F - closed cup
Flash Point (°C)
25 °C - closed cup
이미 열람한 고객
The Journal of organic chemistry, 67(8), 2645-2652 (2002-04-13)
Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl(pyridyl)silane is described. The hydrosilylation of alkenes using dimethyl(2-pyridyl)silane (2-PyMe(2)SiH) proceeded well in the presence of a catalytic amount of RhCl(PPh(3))(3) with virtually complete regioselectivity. By taking advantage of the phase tag property
Practical access to amines by platinum-catalyzed reduction of carboxamides with hydrosilanes: synergy of dual Si- H groups leads to high efficiency and selectivity
Journal of the American Chemical Society, 131, 15032-15040 (2009)
Ionic liquids as solvents for rhodium and platinum catalysts used in hydrosilylation reaction
Molecules (Basel), 21, 1115-1115 (2016)
Platinum (0)-1, 3-divinyl-1, 1, 3, 3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst
Journal of Nanomaterials, 2014 (2014)
Organic Syntheses, 81, 54-54 (2005)
문서
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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