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Merck
모든 사진(1)

주요 문서

모든 문서 보기

512362

Sigma-Aldrich

3-Methylpyridine-2-carboxylic acid

97%

동의어(들):

3-Methylpicolinic acid

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모든 사진(1)

About This Item

실험식(Hill 표기법):
C7H7NO2
CAS Number:
4021-07-2
Molecular Weight:
137.14
MDL number:
MFCD00191553
UNSPSC 코드:
12352100
PubChem Substance ID:
24873626
NACRES:
NA.22

Quality Level

100

분석

97%

형태

solid

mp

114-118 °C

작용기

carboxylic acid

SMILES string

Cc1cccnc1C(O)=O

InChI

1S/C7H7NO2/c1-5-3-2-4-8-6(5)7(9)10/h2-4H,1H3,(H,9,10)

InChI key

LMHIBYREWJHKNZ-UHFFFAOYSA-N

관련 카테고리

일반 설명

3-Methylpyridine-2-carboxylic acid, also known as 3-methylpicolinic acid (3-MepicH), is a 3-substituted picolinic acid. The dianion formed by reacting 3-MepicH with lithium diisopropylamide (LDA) can undergo C-alkylation with 3-chlorobenzyl chloride.

애플리케이션

3-Methylpyridine-2-carboxylic acid (3-MepicH) may be used as a ligand in the synthesis of the following metal complexes:
  • [Cu(3-Mepic)2(4-pic)] where 4-pic=4-picoline and [Cu(3-Mepic)2]·2H2O
  • [Co(3-Mepic)3]
  • [Ni(3-Mepic)2(H2O)2]
  • bis(3-methyl-picolinato-κ2 N,O)(1,10-phenanthroline)zinc(II) tetrahydrate

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
13629MH
06223MH
06208PE
04408HC
00408JC

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Hoi-Ling Seng et al.
Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine, 23(1), 99-118 (2009-09-30)
Crystal structure analysis of the zinc complex establishes it as a distorted octahedral complex, bis(3-methylpicolinato-kappa(2) N,O)(2)(1,10-phenanthroline-kappa(2) N,N)-zinc(II) pentahydrate, [Zn(3-Me-pic)(2)(phen)]x5H(2)O. The trans-configuration of carbonyl oxygen atoms of the carboxylate moieties and orientation of the two planar picolinate ligands above and before
Synthesis and characterization of copper (II) complexes with 3-methylpicolinic acid. Crystal and molecular structure of bis (3-methylpicolinato-N,O)(4-picoline) copper (II).
Kukovec BM, et al.
Journal of Coordination Chemistry, 61(19), 3092-3101 (2008)
Synthesis, structural, spectroscopic and thermal characterization of cobalt complexes with 3-and 6-methylpicolinic acid. Voltammetric and spectrophotometric study in solution.
Kukovec BM, et al.
Inorgorganica Chimica Acta, 362(8), 2704-2714 (2009)
Ozonolysis of some 8-alkoxyquinolines, and synthesis of a precursor to the non-sedating antihistamine Claritin.
Eichler MC and Grayson DH.
ARKIVOC (Gainesville, FL, United States), 6, 38-53 (2014)
Synthesis, X-ray structural, IR spectroscopic, thermal and DFT studies of nickel (II) and copper (II) complexes with 3-methylpicolinic acid. UV-Vis spectrophotometric study of complexation in the solution.
Kukovec BM, et al.
Polyhedron, 52, 1349-1361 (2013)
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