563722
3-Chlorophenylmagnesium bromide
0.5 M in THF
동의어(들):
(3-Chlorophenyl)magnesium bromide, (m-Chlorophenyl)magnesium bromide, 3-chloro phenyl magnesium bromide, 3-chlorophenyl magnesium bromide, m-chlorophenyl magnesium bromide, Bromo(3-chlorophenyl)magnesium
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C6H4BrClMg
CAS Number:
Molecular Weight:
215.76
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
추천 제품
반응 적합성
reaction type: Grignard Reaction
Quality Level
농도
0.5 M in THF
bp
65 °C (lit.)
density
0.960 g/mL at 25 °C (lit.)
작용기
chloro
저장 온도
2-8°C
SMILES string
Clc1cccc([Mg]Br)c1
InChI
1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1
InChI key
ZIYRUWPTUPFRQU-UHFFFAOYSA-M
애플리케이션
3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:
- 2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
- 2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
- 2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.
법적 정보
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
<1.4 °F - closed cup
Flash Point (°C)
< -17 °C - closed cup
The discovery of 4-1-[({2, 5-dimethyl-4-[4-(trifluoromethyl) benzyl]-3-thienyl}carbonyl) amino] cyclopropyl}benzoic acid (MK-2894), a potent and selective prostaglandin E2 subtype 4 receptor antagonist
Blouin M, et al.
Journal of Medicinal Chemistry, 53(5), 2227-2238 (2010)
Novel synthesis of 2, 3-diarylbuta-1, 3-dienes from 1, 4-dimethoxybutyne-2
Ishino Y, et al.
Tetrahedron Letters, 21(16), 1527-1528 (1980)
Synthesis of 3-substituted 3H-indol-3-ols by the reaction of 2-isocyanophenyl ketones with Grignard reagents
Kobayashi K, et al.
Tetrahedron, 66(40), 7961-7964 (2010)
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