661058

Methoxy(cyclooctadiene)rhodium(I) dimer

• 동의어(들): [Rh(OMe)(1,5-cod)]₂
• 실험식(Hill 표기법): C₁₈H₃₀O₂Rh₂
• CAS Number: 12148-72-0
• Molecular Weight: 484.24
• MDL number: MFCD08457639
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24884497
• NACRES: NA.22

속성

• 형태: solid
• 반응 적합성: core: rhodium; reagent type: catalyst
• mp: 192-225 °C
• 저장 온도: −20°C
• SMILES string: CO[Rh].CO[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2CH3O.2Rh/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*-1;2*+1/b2*2-1-,8-7-;;;;
• InChI key: BDQMDBOKWREKIT-MIXQCLKLSA-N

설명

애플리케이션

Efficient and Selective Catalysts for Asymmetric Synthesis

Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation

Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable