662283

Bis(tert-butylcarbonyloxy)iodobenzene

97%

• 동의어(들): (Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene
• 실험식(Hill 표기법): C₁₆H₂₃IO₄
• CAS Number: 57357-20-7
• Molecular Weight: 406.26
• MDL number: MFCD08276835
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24884583
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• 반응 적합성: reagent type: catalyst; reaction type: C-H Activation; reagent type: oxidant
• mp: 104-109 °C
• 작용기: iodo
• SMILES string: CC(C)(C)C(=O)O[I](OC(=O)C(C)(C)C)c1ccccc1
• InChI: 1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
• InChI key: DZKPLZUSZXYHFB-UHFFFAOYSA-N

설명

애플리케이션

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Reagent for:

• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
• Palladium-catalyzed diamination
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
• C-H acyloxylation of arenes

• Hypervalent iodine oxidant

Hypervalent iodine reagent used with the Rh₂(esp)₂ catalyst (662623) in the amination of C-H bonds.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)