모든 사진(1)

주요 문서

COO/COA

모든 문서 보기

667854

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

Name: (+)-1,2-Bis((2<I>S</I>,5<I>S</I>)-2,5-diphenylphospholano)ethane
Brand: ALDRICH

kanata purity

동의어(들):

(S,S)-Ph-BPE,BPE

로그인조직 및 계약 가격 보기

모든 사진(1)

About This Item

실험식(Hill 표기법):

C₃₄H₃₆P₂

CAS Number:

824395-67-7

Molecular Weight:

506.60

MDL number:

MFCD07369028

UNSPSC 코드:

12352005

PubChem Substance ID:

24884945

NACRES:

NA.22

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

667811

(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane

Sigma-Aldrich

665266

(+)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene

Sigma-Aldrich

668435

1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]ethane

Sigma-Aldrich

693065

(R)-BINAP

Sigma-Aldrich

657697

(1R,1′R,2S,2′S)-DuanPhos

Sigma-Aldrich

692484

(R)-DTBM-SEGPHOS^®

Sigma-Aldrich

481084

rac-BINAP

Sigma-Aldrich

668478

(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane

Sigma-Aldrich

328774

Tris(dibenzylideneacetone)dipalladium(0)

Sigma-Aldrich

452882

Sodium borohydride

Quality Level

100

형태

solid

mp

143-147 °C

작용기

phenyl
phosphine

SMILES string

C1C[C@H](P(CCP2[C@@H](CC[C@H]2c3ccccc3)c4ccccc4)[C@@H]1c5ccccc5)c6ccccc6

InChI

1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m0/s1

InChI key

VHHAZLMVLLIMHT-CUPIEXAXSA-N

일반 설명

Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides

Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study