모든 사진(1)

주요 문서

COO/COA

모든 문서 보기

675334

(S)-VAPOL

Name: (<I>S</I>)-VAPOL
Brand: ALDRICH

97%

동의어(들):

(S)-2,2′-Diphenyl-(4-biphenanthrol)

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모든 사진(1)

About This Item

실험식(Hill 표기법):

C₄₀H₂₆O₂

CAS Number:

147702-15-6

Molecular Weight:

538.63

EC Number:

200-838-9

MDL number:

MFCD11617354

UNSPSC 코드:

12352005

PubChem Substance ID:

24885273

NACRES:

NA.22

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

675156

(R)-VANOL

Sigma-Aldrich

676098

(S)-VANOL

Sigma-Aldrich

675210

(R)-VAPOL

Sigma-Aldrich

595721

(R)-(+)-3,3′-Dibromo-1,1′-bi-2-naphthol

Sigma-Aldrich

246948

(R)-(+)-1,1′-Bi(2-naphthol)

Sigma-Aldrich

674591

(R)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol

Sigma-Aldrich

700673

(R)-3,3′-Di-9-phenanthrenyl-1,1′-bi-2-naphthol

Sigma-Aldrich

674737

(R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol

Sigma-Aldrich

246956

(S)-(−)-1,1′-Bi(2-naphthol)

Sigma-Aldrich

104655

1,1′-Bi-2-naphthol

Quality Level

100

분석

97%

형태

solid

광학 활성

[α]20/D 128°, c = 1 in chloroform

mp

185-191 °C

작용기

phenyl

SMILES string

Oc1c(c(cc2ccc3ccccc3c12)-c4ccccc4)-c5c(O)c6c(ccc7ccccc67)cc5-c8ccccc8

InChI

1S/C40H26O2/c41-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)42/h1-24,41-42H

InChI key

UFYXKDMLGBKHIC-UHFFFAOYSA-N

애플리케이션

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

픽토그램

GHS08,GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H351

예방조치 성명서

P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 2

1 of 2

Sigma-Aldrich

674591

(R)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol

Sigma-Aldrich

681520

(S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

A dual chromophore sensor for the detection of amines, diols, hydroxy acids, and amino alcohols.

Mariia Pushina et al.

Chemical communications (Cambridge, England), 55(31), 4495-4498 (2019-03-29)

The determination of enantiomeric excess (ee) in various groups of chiral compounds, namely amines, amino alcohols, diols, and hydroxy acids is performed using a dual chromophore FRET/PET based sensor ensemble. The sensing ensemble utilizes fluorescence changes from two chromophores (indicators)

Bao. J. et al.

Journal of the American Chemical Society, 118, 3392-3392 (1996)

New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.

Su Yu et al.

Organic letters, 7(3), 367-369 (2005-01-28)

[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus.

Highly enantioselective deracemization of linear and vaulted biaryl ligands.

Yu Zhang et al.

Organic letters, 5(11), 1813-1816 (2003-05-24)

[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible formation of

주요 문서

(S)-VAPOL

97%

About This Item

추천 제품

속성

Quality Level

분석

형태

광학 활성

mp

작용기

SMILES string

InChI

InChI key

관련 카테고리

설명

애플리케이션

안전성 정보

픽토그램

신호어

유해 및 위험 성명서

예방조치 성명서

Hazard Classifications

Storage Class Code

WGK

Flash Point (°F)

Flash Point (°C)

문서

시험 성적서(COA)

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