675512

(R)-(–)-VAPOL hydrogenphosphate

• 동의어(들): (R)-2,2′-Diphenyl-3,3′-biphenanthryl-4,4′-diyl phosphate, (R)-VAPOL phosphoric acid, 18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3′,4′-f][1,3,2]dioxaphosphepin-18-oxide
• 실험식(Hill 표기법): C₄₀H₂₅O₄P
• CAS Number: 871130-18-6
• Molecular Weight: 600.60
• MDL number: MFCD09265084
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24885284
• NACRES: NA.22

속성

• 형태: solid
• Quality Level: 100
• SMILES string: OP1(=O)Oc2c(c(cc3ccc4ccccc4c23)-c5ccccc5)-c6c(O1)c7c(ccc8ccccc78)cc6-c9ccccc9
• InChI: 1S/C40H25O4P/c41-45(42)43-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)44-45/h1-24H,(H,41,42)
• InChI key: YKIJNEDTUDPMNC-UHFFFAOYSA-N

설명

애플리케이션

Catalyst involved in:

• Desymmetrization of meso-aziridines
• Asymmetric aza-Darzens aziridine synthesis
• Enantioselective ring-opening of mono-and bicyclic N-acyl meso aziridines
• Condensation of aldehydes with amino benzenesulfonamides
• Pictet-Spengler reactions

Useful chiral Bronsted acid catalyst in the addition of sulfonamides to Boc-activated aryl imines.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable