695459

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

97%

• 동의어(들): 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.1^3,7]decane, ^meCgPPh
• 실험식(Hill 표기법): C₁₆H₂₁O₃P
• CAS Number: 97739-46-3
• Molecular Weight: 292.31
• MDL number: MFCD30541356
• UNSPSC 코드: 12352005
• PubChem Substance ID: 329761744
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• 반응 적합성: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• mp: 106-111 °C
• 작용기: phosphine
• SMILES string: CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2
• InChI: 1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
• InChI key: AVVSJWUWBATQBX-UHFFFAOYSA-N

설명

애플리케이션

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:

• As a ligand to synthesize complexes for hydroformylation catalysis.
• To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable