710326

(1,3-Dioxolan-2-ylmethyl)zinc bromide

0.6 M in THF

• 실험식(Hill 표기법): C₄H₇BrO₂Zn
• Molecular Weight: 232.39
• MDL number: MFCD07698709
• UNSPSC 코드: 12352005
• PubChem Substance ID: 329762915
• NACRES: NA.22

속성

• 양식: liquid
• Quality Level: 100
• 반응 적합성: reaction type: C-C Bond Formation
• 농도: 0.6 M in THF
• density: 0.992 g/mL at 25 °C
• 작용기: ether
• 저장 온도: 2-8°C
• SMILES string: Br[Zn]CC1OCCO1
• InChI: 1S/C4H7O2.BrH.Zn/c1-4-5-2-3-6-4;;/h4H,1-3H2;1H;/q;;+1/p-1
• InChI key: LOJRLQRGBKTHDB-UHFFFAOYSA-M

설명

일반 설명

(1,3-Dioxolan-2-ylmethyl)zinc bromide is an organozinc compound used as a reagent in Negishi cross-coupling reaction to prepare aryl or heteroaryl scaffolds via C-C bond formation.

애플리케이션

(1,3-Dioxolan-2-ylmethyl)zinc bromide can be used as a reagent in the allylic alkylation reactions in the presence of iridium catalyst.

법적 정보

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H315,H319,H335,H336,H351
• 예방조치 성명서: P202 - P210 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -22.0 °F
• Flash Point (°C): -30 °C