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Merck
모든 사진(3)

주요 문서

757136

Sigma-Aldrich

Lithium bis(oxalato)borate

greener alternative

동의어(들):

LiBOB, Lithium bis(ethanedioato)borate, Lithium bis(oxalate)borate

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About This Item

Linear Formula:
LiB(C2O4)2
CAS Number:
Molecular Weight:
193.79
MDL number:
UNSPSC 코드:
26111700
PubChem Substance ID:
NACRES:
NA.23

형태

powder or crystals

Quality Level

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (lit.)

응용 분야

battery manufacturing

환경친화적 대안 카테고리

SMILES string

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

InChI key

NVQAYVUCVASGDK-UHFFFAOYSA-N

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일반 설명

Lithium bis(oxalato)borate (LiBOB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

애플리케이션

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.
LiBOB is a thermally stable electrolyte that can be used to protect graphite-based anode materials in lithium-ion batteries. It shows good electrochemical performance with a discharge capacity retention of ~ 83%.

법적 정보

Product of Albemarle US Inc

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Surface layer formed on silicon thin-film electrode in lithium bis (oxalato) borate-based electrolyte
Choi N, et al.
Journal of Power Sources, 172(1), 404-409 (2007)
Snehashis Choudhury et al.
Nature communications, 10(1), 4398-4398 (2019-09-29)
Electrochemical cells based on alkali metal anodes are receiving intensive scientific interest as potentially transformative technology platforms for electrical energy storage. Chemical, morphological, mechanical and hydrodynamic instabilities at the metal anode produce uneven metal electrodeposition and poor anode reversibility, which, are among the many
On the electrochemical and thermal behavior of lithium bis (oxalato) borate (LiBOB) solutions
Larush-Asraf L, et al.
Journal of Power Sources, 174(2), 400-407 (2007)
Wengao Zhao et al.
ChemSusChem, 11(13), 2211-2220 (2018-05-03)
The long-term cycling performance, rate capability, and voltage stability of lithium (Li) metal batteries with LiNi0.76 Mn0.14 Co0.10 O2 (NMC76) cathodes is greatly enhanced by lithium bis(oxalato)borate (LiBOB) additive in the LiPF6 -based electrolyte. With 2 % LiBOB in the electrolyte
Lithium bis (oxalato) borate stabilizes graphite anode in propylene carbonate
Xu K, et al.
Electrochemical and Solid-State Letters, 5(11), A259-A259 (2002)

문서

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

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