449504

Bis(trifluoromethane)sulfonimide lithium salt

• 동의어(들): Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate
• Linear Formula: CF₃SO₂NLiSO₂CF₃
• CAS Number: 90076-65-6
• Molecular Weight: 287.09
• Beilstein: 6625414
• EC Number: 415-300-0
• MDL number: MFCD00210017
• UNSPSC 코드: 12352302
• PubChem Substance ID: 24868486
• NACRES: NA.22

속성

• mp: 234-238 °C (lit.)
• 작용기: fluoro
• SMILES string: [Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
• InChI: 1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
• InChI key: QSZMZKBZAYQGRS-UHFFFAOYSA-N

설명

애플리케이션

Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) can be used:

• As a chemical additive for improving the power conversion efficiencies in porphyrin-based organic solar cells.     
• As a reagent in the preparation of imidazolium core bearing monomer ionic liquids to develop polymerized ionic liquids.
• For the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate.       
• In the synthesis of solid polymer electrolytes for lithium-ion batteries. 
• In the synthesis of polyelectrolyte reusable homogenous catalysts, which are used in the Diels–Alder reactions between isoprene and a variety of dienophiles.
• Used in the preparation of electrolytes for lithium batteries and novel rare-earth Lewis acid catalysts.

기타 정보

For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.

안전성 정보

• 픽토그램: GHS06,GHS08,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H311,H314,H373,H412
• 예방조치 성명서: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral
• 표적 기관: Nervous system
• Storage Class Code: 6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges