911828

PhPAd-DalPhos Ni(o-tolyl)Cl

≥95%

• 동의어(들): (SP-4-3)-Chloro[8-[2-(diphenylphosphino-κP)phenyl]-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane-κP8](2-methylphenyl)nickel
• 실험식(Hill 표기법): C₃₅H₃₇ClNiO₃P₂
• CAS Number: 2290490-29-6
• Molecular Weight: 661.76
• UNSPSC 코드: 12161600
• NACRES: NA.22

속성

• 분석: ≥95%
• 형태: powder
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings
• mp: 235-248 °C
• SMILES string: Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C

설명

애플리케이션

PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes.

기타 정보

Technology Spotlight: DalPhos ligands

PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines

안전성 정보

• 픽토그램: GHS08,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H302 + H332,H334,H341,H351,H361f,H372,H410
• 예방조치 성명서: P202 - P260 - P264 - P273 - P301 + P312 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable